Hierarchical 3D Cuprous Sulfide Nanoporous Cluster Arrays Self‐Assembled on Copper Foam as a Binder‐Free Cathode for Hybrid Magnesium‐Based Batteries

Abstract

On account of easy accessibility, high theoretical volumetric capacity and dendrite-free magnesium (Mg) anode, Mg battery has a great promise to be next generation rechargeable batteries, yet still remains a challenging task in acquiring fast Mg²⁺ kinetics and effective cathode materials. Herein, hierarchical 3D cuprous sulfide porous nanosheet decorated nanowire cluster arrays with robust adhesion on copper foam (Cu₂ S HP/CF), which is employed as a binder-free conversion cathode material for magnesium/lithium hybrid battery, delivering impressively initial and reversible specific capacity of 383 and 311 mAh g^-1 at 100 mA g^-1 , respectively, which are obviously outperformed corresponding powder cathode in a traditional method by using polymer binder, is reported. Intriguingly, benefiting from the hierarchical nanoporous array architecture and self-assembly feature, Cu₂ S HP/CF cathode shows a remarkable cycling stability with a high capacity of 129 mAh g^-1 at 300 mA g^-1 over 500 cycles. This work not only highlights a guide for designing hierarchical nanoporous materials derived from metal-organic frameworks, but also provides a novel strategy of in situ formation to fabricate binder-free cathodes.