High‐Performance Electrochemical NO Reduction into NH₃ by MoS₂ Nanosheet

Abstract

Electrochemical reduction of NO not only offers an attractive alternative to the Haber-Bosch process for ambient NH₃ production but mitigates the human-caused unbalance of nitrogen cycle. Herein, we report that MoS₂ nanosheet on graphite felt (MoS₂ /GF) acts as an efficient and robust 3D electrocatalyst for NO-to-NH₃ conversion. In acidic electrolyte, such MoS₂ /GF attains a maximal Faradaic efficiency of 76.6 % and a large NH₃ yield of up to 99.6 μmol cm^-2 h^-1 . Using MoS₂ nanosheet-loaded carbon paper as the cathode, a proof-of-concept device of Zn-NO battery was assembled to deliver a discharge power density of 1.04 mW cm^-2 and an NH₃ yield of 411.8 μg h^-1 mg_cat. ^-1 . Calculations reveal that the positively charged Mo-edge sites facilitate NO adsorption/activation via an acceptance-donation mechanism and disfavor the binding of protons and the coupling of N-N bond.