Modulating Tri‐Mode Emission for Single‐Component White Organic Afterglow

Abstract

Achieving single-component white organic afterglow remains a great challenge owing to the difficulties in simultaneously supporting long-lived emissions from varied excited states of a molecule for complementary afterglow. Here, an extraordinary tri-mode emission from the radiative decays of singlet (S₁ ), triplet (T₁ ), and stabilized triplet (T₁ ^* ) excited states was proposed to afford white afterglow through modulating the singlet-triplet splitting energy (ΔE_ST ) and exciton trapping depth (E_TD ). Low-lying T₁ * for yellow afterglow was constructed by H-aggregation engineering with large E_TD and trace isomer doping, while high-lying T₁ and S₁ for blue afterglow with thermally activated emission feature were realized by reducing ΔE_ST through donor-acceptor molecular design. Therefore, the single-component white afterglow with high efficiency of 14.1 % and a lifetime of 0.61 s was achieved by rationally regulating the afterglow intensity ratios of complementary emissions from S₁ , T₁ , and T₁ *.