Sunlight driven photocatalytic degradation of organic pollutants using a MnV₂O₆/BiVO₄ heterojunction: mechanistic perception and degradation pathways

Abstract

In the field of photocatalysis, fabrication of a heterojunction structure with effective charge separation at the interface and charge shift to enhance the photocatalytic activity has acquired extensive consideration. In the present investigation, MnV₂O₆/BiVO₄ heterojunction samples with excellent photocatalytic performance under sunlight irradiation were conveniently synthesized by a hydrothermal technique, and characterized by UV-Vis, FTIR, XRD, FESEM, HRTEM, PL, BET and XPS techniques. The prepared samples were investigated as photocatalysts for degrading MB and RhB dyes under sunlight. Among various samples of MnV₂O₆/BiVO₄, the S-V hetero-junction sample exhibited maximum photocatalytic activity with 98% and 96% degradation of MB and RhB dyes, respectively, in 6 and 35 min. The high photocatalytic activity of MnV₂O₆/BiVO₄ may be due to the successful generation and shift of charges in the presence of visible light. The average reduction of chemical oxygen demand (COD) was found to be 75% after irradiation with direct sunlight. In the degradation process of dyes, superoxide anion radicals were the main responsive species, as revealed by trapping experiments. The degradation efficiency of MnV₂O₆/BiVO₄ heterojunction did not diminish even after four cycles. In addition, the catalytic performance of the fabricated heterojunction was also explored for reducing 4-nitrophenols (4-NP) by using NaBH₄. Absolute conversion of 4-NP to 4-aminophenol (4-AP) occurred without the production of intermediate byproducts.