Self‐Hybrid Transition Metal Oxide Nanosheets Synthesized by a Facile Programmable and Scalable Carbonate‐Template Method

Abstract

2D transition metal oxides (TMO) nanosheets have attracted considerable attention in both fundamental research and practical applications. Herein, a convenient programmable and scalable carbonate crystals templating synthesis is developed to produce high-quality self-hybrid TMO nanosheets (Si-WO_3- _x , Ta_x O_y , Mn_x O_y ) and their respective polymetallic oxide hybrid nanosheets with tunable composition, low-cost and high-yield. Taking tungsten oxide nanosheets as example, silicotungstic acid precursor is in situ converted into tungsten oxide nanosheets like scales on the surface of calcium carbonate crystals through the simple soaking-drying-calcination process, and after selectively dissolving calcium carbonate by etching, the dispersive tungsten oxide nanosheets with unique self-hybrid Si-doped h-WO₃ /ε-WO₃ /WO₂ compositions are obtained, which show excellent acetone gas-sensing performances at low temperatures. This carbonate-template method opens up the possibility to economically produce various functional TMO nanosheets with specific compositions for diverse applications.