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Ruthenium(II)/Chiral Carboxylic Acid Catalyzed Enantioselective C–H Functionalization of Sulfoximines
41
Citations
71
References
2021
Year
Sulfoxonium YlidesChemical EngineeringEngineeringAbstract RutheniumOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryS-chiral ProductsAsymmetric CatalysisSynthetic ChemistryEnantioselective Synthesis
Abstract Ruthenium(II)-catalyzed enantioselective C–H functionalization reactions of sulfoximines with sulfoxonium ylides are described. The combination of [RuCl2(p-cymene)]2 and a pseudo-C 2-symmetric binaphthyl monocarboxylic acid furnished the S-chiral products in 76:24 to 92:8 er.
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