Polymer Chemistry · 2021 · 11 citations · 59 references
Natural SciencesChemistryMaterials ScienceOrganic ChemistryPolymer ChemistryPolymer MaterialsPhotochemical SynthesisPolymer ProcessingPolymer StructurePolymer SynthesisPolymerization ChemistryPolymerization ProcessesBlock Copolymer SynthesisChemical PolymerizationCopolymerization StrategiesPhotopolymerizationPolyester Synthesis
In a “one organocatalyst, two polymerizations” system, triarylsulfonium hexafluorophosphate salt could spontaneously catalyze photo-ATRP and ROP. A well-defined PTMC- b -PMMA block copolymer was successfully synthesized in one-step.
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Metal-Free Atom Transfer Radical Polymerization
Nicolas J. Treat, Hazel Sprafke, John W. Kramer et al. · Journal of the American Chemical Society · 2014 · 928 citations · Full text