ACS Central Science · 2021 · 74 citations · 39 references
Natural SciencesChemistryMaterials ScienceElectrochemistryInorganic ChemistrySurface ScienceElectrochemical Energy ConversionElectrochemical SynthesisElectrode MaterialsElectrode-electrolyte InterfacesMetal Framework FabricationRedox-active MaterialsInterfacial ChemistryMetal-organic Framework Redox MaterialsMetal-organic Framework SynthesisMetal-organic FrameworksModified ElectrodesOxidationOxidation - Reduction PotentialOxidation-reduction Potential
) in a solution containing 2,6-lutidine and terephthalic acid affords highly crystalline Fe-MIL-101. Controlled potential electrolysis with carboxy-functionalized ITO affords Fe-MIL-101 grown directly on the surface of modified electrodes. The methods we report herein represent the first general routes that employ interfacial electrochemistry to alter the oxidation state of metal ions dissolved in solution to directly trigger MOF formation. The reported method is functional group tolerant and will be broadly applicable to the bulk synthesis or surface growth of a range of MOFs based on metal ions with accessible oxidation states.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Hailian Li, Mohamed Eddaoudi, M. O’Keeffe et al. · Nature · 1999 · 8.4K citations · Full text
Metal–organic frameworks—prospective industrial applications
U. Müeller, Markus M. Schubert, F. Teich et al. · Journal of Materials Chemistry · 2005 · 2.3K citations
Natural Sciences, Materials Engineering, Materials Science +17