Carbon Nanoparticles of Varying Shapes as Additives in Mineral Oil Assessment of Comparative Performance Potential

Abstract

In this work, carbonaceous nanoparticles (NPs) of varying morphology, viz., multilayer graphene (lamellar, thickness ∼ 3-7 nm), graphite (spherical ∼70 nm), and multi-walled carbon nanotubes (tubular), were selected to explore their tribo-potential in oil under identical operating conditions. A series of nano-oils were prepared using API group III mineral base oil with a dispersant (1%) and selected NPs in incremental concentration (0.5-4%). The tribo-performance of oils was evaluated on a four-ball tester and SRV-IV for extreme-pressure, antiwear (AW), and antifriction performance. Formulations were characterized for density, viscosity, and viscosity index. The stability of oils was monitored through visual observation weekly. Results revealed that the graphene particles showed excellent wear-preventive ability as an AW additive with (41-50) % increase followed by nanographite. Worn surfaces were studied to understand the plausible wear mechanism using a different spectroscopic technique. Tribo-behavior performance was supported with lateral force microscopy on the surfaces of tribo-films.