Glutathione-functionalized long-period fiber gratings sensor based on surface plasmon resonance for detection of As ³⁺ ions

Abstract

Development of simple and accurate methods for the detection of As³⁺is highly desirable and technically important. In this work, a highly sensitive and selective long-period fiber gratings sensor based on surface plasmon resonance was developed for As³⁺detection by designing glutathione-functionalized Au nanoparticles as a signal amplification tag. Based on the chemical interaction between As³⁺and glutathione, the self-assembling glutathione on the surface of the gold film combines selectively with As³⁺, and then anchors the glutathione-functionalized Au nanoparticles, which changes the refractive index of the surrounding environment, resulting in a shift of the transmission spectrum. Results show that the sensor could detect As³⁺with concentrations ranging from 0.02 to 2 ppb. The sensor exhibited excellent specificity for As³⁺against other metal ions, such as Na⁺, Fe³⁺, Mg²⁺, Cu²⁺, Pb²⁺, Ni²⁺, Ba²⁺, and Co³⁺. The fiber sensor was successfully employed to detect As³⁺in pond water samples, demonstrating that it has the potential for As³⁺detection with the advantages of low cost, high sensitivity, and a simple structure.