Bimetallic Sulfide SnS₂/FeS₂ Nanosheets as High-Performance Anode Materials for Sodium-Ion Batteries

Abstract

Transition-metal sulfide SnS₂ has aroused wide concern due to its high capacity and nanosheet structure, making it an attractive choice as the anode material in sodium-ion batteries. However, the large volume expansion and poor conductivity of SnS₂ lead to inferior cycle stability as well as rate performance. In this work, FeS₂ was in situ introduced to synchronously grow with SnS₂ on rGO to prepare a heterojunction bimetallic sulfide nanosheet SnS₂/FeS₂/rGO composite. The composition and distinctive structure facilitate the rapid diffusion of Na⁺ and improve the charge transfer at the heterogeneous interface, providing sufficient space for volume expansion and improving anode materials' structural stability. SnS₂/FeS₂/rGO bimetallic sulfide electrode boasts a capacity of 768.3 mA h g^-1 at the current density of 0.1 A g^-1, and 541.2 mA h g^-1 at the current density of 1 A g^-1 in sodium-ion batteries, which is superior to that of either single metal sulfide SnS₂ or FeS₂. TDOS calculation further confirms that the binding of FeS₂/SnS₂-Na is more stable than FeS₂ and SnS₂ alone. The superior electrochemical performance of the SnS₂/FeS₂/rGO composite material makes it a promising candidate for sodium storage.