Hydroboration of aldehydes, ketones and CO₂ under mild conditions mediated by iron(<scp>iii</scp>) salen complexes

Abstract

The hydroboration of aldehydes, ketones and CO₂ is demonstrated using a cheap and air stable [Fe(salen)]₂-μ-oxo pre-catalyst with pinacolborane (HBpin) as the reductant under mild conditions. This catalyst system chemoselectively hydroborates aldehydes over ketones and ketones over alkenes. In addition, the [Fe(salen)₂]-μ-oxo pre-catalyst shows good efficacy at reducing "wet" CO₂ with HBpin at room temperature.