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Synthetic studies on cell surface glycans. Part XVIII. Synthetic studies on nephritogenic glycosides. Synthesis of N-(.BETA.-L-aspartyl)-.ALPHA.-D-glucopyranosylamine.
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1983
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Cell Surface GlycansBioorganic ChemistryKey IntermediatePart StructureGlycobiologyNephritogenic GlycopeptideGlycoproteomicsBiosynthesisStereoselective SynthesisGlycosylationProtein GlycosylationBiochemistryDiversity-oriented SynthesisBioconjugationPharmacologyBio-orthogonal ChemistryBiomolecular EngineeringNephritogenic GlycosidesSynthetic StudiesNatural SciencesPeptide SynthesisMedicineCarbohydrate-protein Interaction
A route for the stereoselective synthesis of N-(β-L-aspartyl)-α-D-glucopyranosylamine, a part structure of the nephritogenic glycopeptide, was developed by using 2, 3, 4, 6-tetra-O-benzyl-α-D-glucopyranosyl azide as a key intermediate.