Facile Preparation of MoS₂ Nanocomposites for Efficient Potassium‐Ion Batteries by Grinding‐Promoted Intercalation Exfoliation

Abstract

Efficient exfoliations of bulk molybdenum disulfide (MoS₂ ) into few-layered nanosheets in pure phase are highly attractive because of the promising applications of the resulted 2D materials in diversified optoelectronic devices. Here, a new exfoliation method is presented to prepare semiconductive 2D hexagonal phase (2H phase) MoS₂ -cellulose nanocrystal (CNC) nanocomposites using grinding-promoted intercalation exfoliation (GPIE). This method with facile grinding of the bulk MoS₂ and CNC powder followed by conventional liquid-phase exfoliation in water can not only efficiently exfoliate 2H-MoS₂ nanosheets, but also produce the 2H-MoS₂ /CNC 2D nanocomposites simultaneously. Interestingly, the intercalated CNC sandwiched in MoS₂ nanosheets increases the interlayer spacing of 2H-MoS₂ , providing perfect conditions to accommodate the large-sized ions. Therefore, these nanocomposites are good anode materials of potassium-ion batteries (KIBs), showing a high reversible capacity of 203 mAh g^-1 at 200 mA g^-1 after 300 cycles, a good reversible capacity of 114 mAh g^-1 at 500 mA g^-1 , and a low decay of 0.02% per cycle over 1500 cycles. With these impressive KIB performances, this efficient GPIE method will open up a new avenue to prepare pure-phase MoS₂ and promising 2D nanocomposites for high-performance device applications.