Highly conductive graphite matrix/copper composites by a pressureless infiltration method

Abstract

Graphite matrix/copper composites have found significant potential uses in numerous areas. Until now, a high ambient gas pressure has to be applied to overcome the non-wettability between the copper melt and graphite matrix, which has restricted the technological and economic efficiencies, as well as the composite performance. In this paper, we have proposed a pressureless infiltration strategy to realize the preparation of highly conductive graphite matrix/copper composites. A tungsten carbide network is first in situ constructed in the graphite matrix, transforming the capillary force from the resistance mode to the impetus mode. Results show that the contact angle of graphite/copper decreased from 138.5° to 23° due to the constructed tungsten carbide network. The composites exhibit good interfacial bonding, and the electrical conductivity reaches 15.1 × 105 S/m, far higher than the requirement of the industry standard.