A Flexible Self‐Powered UV Photodetector and Optical UV Filter Based on β‐Bi₂O₃/SnO₂ Quantum Dots Schottky Heterojunction

Abstract

Abstract Recently reported ultraviolet (UV) detectors majorly focus on exploration of photodetection properties like photon absorption and electron‐hole pair generation to improve the photoresponsivity. However, UV sensors also have a potential advantage of monitoring the excessive UV exposure on skin. In this work, bismuth oxide/SnO 2 quantum dots (QDs) vertical‐junction‐based self‐powered UV photodetector and optical UV filter are demonstrated. β‐Bi 2 O 3 nanofibers are synthesized via electrospinning technique and SnO 2 QDs are synthesized using a facile, single step hydrothermal process. Detailed morphological studies reveal the formation of 1D‐Bi 2 O 3 and 0D‐SnO 2 . The fabricated self‐powered Bi 2 O 2 /SnO 2 ‐based p–n heterojunction device exhibits a maximum responsivity of 62.5 µ A W −1 and specific detectivity (D*) of 4.5 × 109 Jones attributing to the high absorption coefficient of β‐Bi 2 O 2 nanofibers and SnO 2 QDs in the UV region. Further, the 1D β‐Bi 2 O 3 nanofibers and 0D SnO 2 QDs are coated onto disposable cloth substrate to fabricate the UV optical filter which exhibits an exceptional ultraviolet protection factor of 159 and the photodetector device demonstrates high stability and reproducibility even after 1000 bending cycles. The strategy outlined here paves the way for development of bifunctional, cost‐effective design and construction of wearable UV sensors and protective devices for advanced nano‐electronic applications.