Ordered PdCu-Based Core–Shell Concave Nanocubes Enclosed by High-Index Facets for Ethanol Electrooxidation

Abstract

Crystal phase engineering is a powerful strategy for regulating the performance of electrocatalysts toward many electrocatalytic reactions. Herein we demonstrate that Au@Pd₁Cu concave nanocubes (CNCs) with an ordered body-centered cubic (bcc) PdCu alloy shell enclosed by many high active high-index facets can be adopted as highly active yet stable electrocatalysts for the ethanol oxidation reaction (EOR). These CNCs are more efficient than other nanocrystals with a disordered face-centered cubic (fcc) PdCu alloy surface and display high mass and specific activities of 10.59 A mg_pd^-1 and 33.24 mA cm^-2, which are 11.7 times and 4.1 times higher than those of commercial Pd black, respectively. Our core-shell CNCs also exhibit robust durability with the weakest decay in activity after 250 potential-scanning cycles, as well as outstanding antipoisoning ability. Alloying with Cu and the ordered bcc phase surface can provide abundant OH_ads species to oxidize carbonaceous poison to avoid catalyst poisoning, and the exposed high-index facets on the surface can act as highly catalytic sites.