Tuning Electrocatalytic Aptitude by Incorporating α-MnO₂ Nanorods in Cu-MOF/rGO/CuO Hybrids: Electrochemical Sensing of Resorcinol for Practical Applications

Abstract

In this study, Cu-MOF/rGO/CuO/α-MnO₂ nanocomposites have been fabricated by a one-step hydrothermal method and used in the voltammetric detection of resorcinol (RS). The poor conductivity of MOFs in the field of electrochemical sensing is still a major challenge. A series of Cu-MOF/rGO/CuO/α-MnO₂ nanocomposites have been synthesized with varying fractions of rGO and with a fixed amount of α-MnO₂ via a facile method. These nanocomposites are well characterized using some sophisticated characterization techniques. The as-prepared nanohybrids have strongly promoted the redox reactions at the electrode surface due to their synergistic effects of improved conductivity, high electrocatalytic activity, an enlarged specific surface area, and a plethora of nanoscale level interfacial collaborations. The electrode modified with Cu-MOF/rGO/CuO/α-MnO₂ has revealed superior electrochemical properties demonstrating linear differential pulse voltammetry (DPV) responses from a 0.2 to 22 μM RS concentration range (<i>R</i>² = 0.999). The overall results of this sensing podium have shown excellent stability, good recovery, and a low detection limit of 0.2 μM. With excellent sensing performance achieved, the practicability of the sensor has been evaluated to detect RS in commercial hair color samples as well as in tap water and river water samples. Therefore, we envision that our hybrid nanostructures synthesized by the structural integration strategy will open new horizons in material synthesis and biosensing platforms.