Room-Temperature Methane Activation Mediated by Free Tantalum Cluster Cations: Size-by-Size Reactivity

Abstract

The energetics of small cationic tantalum clusters and their gas-phase adsorption and dehydrogenation reaction pathways with methane are investigated with ion-trap experiments and spin-density-functional-theory calculations. Ta_<i>n</i>⁺ clusters are exposed to methane under multicollision conditions in a cryogenic ring electrode ion-trap. The cluster size affects the reaction efficiency and the number of consecutively dehydrogenated methane molecules. Small clusters (<i>n</i> = 1-4) dehydrogenate CH₄ and concurrently eliminate H₂, while larger clusters (<i>n</i> > 4) demonstrate only molecular adsorption of methane. Unique behavior is found for the Ta⁺ cation, which dehydrogenates consecutively up to four CH₄ molecules and is predicted theoretically to promote formation of a [Ta(CH₂-CH₂-CH₂)(CH₂)]⁺ product, exhibiting C-C coupled groups. Underlying mechanisms, including reaction-enhancing couplings between potential energy surfaces of different spin-multiplicities, are uncovered.