Carbonyl‐rich Poly(pyrene‐4,5,9,10‐tetraone Sulfide) as Anode Materials for High‐Performance Li and Na‐Ion Batteries

Abstract

Organic carbonyl electrode materials are widely employed for alkali metal-ion secondary batteries in terms of their sustainability, structure designability and abundant resources. As a typical redox-active organic electrode materials, pyrene-4, 5, 9, 10-tetraone (PT) shows high theoretical capacity due to the rich carbonyl active sites. But its electrochemical behavior in secondary batteries still needs further exploration. Herein, PT-based linear polymers (PPTS) is synthesized with thioether bond as bridging group and then employed as an anode material for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). As expected, PPTS shows improved conductivity and insolubility in the non-aqueous electrolyte. When used as an anode material for LIBs, PPTS delivers a high reversible specific capacity of 697.1 mAh g^-1 at 0.1 A g^-1 and good rate performance (335.4 mAh g^-1 at 1 A g^-1 ). Moreover, a reversible specific capacity of 205.2 mAh g^-1 at 0.05 A g^-1 could be obtained as an anode material for SIBs.