TADF‐Type Organic Afterglow

Abstract

We report a highly efficient dopant-matrix afterglow system enabled by TADF mechanism to realize afterglow quantum yields of 60-70 %, which features a moderate rate constant for reverse intersystem crossing (k_RISC ) to simultaneously improve afterglow quantum yields and maintain afterglow emission lifetime. Difluoroboron β-diketonate (BF₂ bdk) compounds are designed with multiple electron-donating groups to possess moderate k_RISC values and are selected as luminescent dopants. The matrices with carbonyl functional groups such as phenyl benzoate (PhB) have been found to interact with and perturb BF₂ bdk excited states by dipole-dipole interactions and thus enhance the intersystem crossing of BF₂ bdk excited states. Through dopant-matrix collaboration, the efficient TADF-type afterglow materials have been achieved to exhibit excellent processability into desired shapes and large-area films by melt casting, as well as aqueous afterglow dispersions for potential bioimaging applications.