Heterogeneous nanocomposites consisting of Pt₃Co alloy particles and CoP₂ nanorods towards high‐efficiency methanol electro‐oxidation

Abstract

Abstract Heterogeneous nanocomposites comprising chemically distinct constituents are particularly promising in electrocatalysis. We herein report a synthetic strategy that combines the reduction of Pt and Co ionic precursors at an appropriate ratio with the subsequent phosphating at an elevated temperature for forming heterogeneous nanocomposites consisting of quasi‐spherical Pt 3 Co alloy domains and rod‐like CoP 2 domains for high‐efficiency methanol electro‐oxidation. The strong electronic coupling between Pt 3 Co and CoP 2 domains in the nanocomposites render the electron density around Pt atoms to decrease, which is favorable for reducing the adsorption of poisoning CO‐like intermediates on the catalyst surfaces. Accordingly, the as‐prepared heterogeneous Pt 3 Co–CoP 2 nanocomposites show good performance for methanol electro‐oxidation both in acidic and alkaline media. In specific, at a Pt loading of only 6.4% on a common carbon substrate, the mass‐based activity of Pt 3 Co–CoP 2 nanocomposites in an acidic medium is about 2 and 1.5 times as high as that of commercial Pt/C catalyst (20% mass loading) and home‐made Pt 3 Co alloy nanoparticles (8.0% mass loading), while in the alkaline medium, these values are 3 and 2, respectively.