Topological Radiated Dendrites Featuring Persistent Bactericidal Activity for Daily Personal Protection

Abstract

Many substances in nature show radiated topological structure and possess excellent bio-adhesion ability. Herein, regulating the topological structure of Zn₂ GeO₄ :Mn persistent phosphors is achieved with a molecular coordination method. The morphology of the Zn₂ GeO₄ :Mn phosphors is well-tuned from nanorods to radiated dendrites by changing the coordination capability of the surface ligand. Due to the structural matching and multivalent interactions, Zn₂ GeO₄ :Mn radiated dendrites show strong adhesion affinity toward organisms. Moreover, the porous radiated structure offers Zn₂ GeO₄ :Mn with a large surface area for photocatalysis. Efficient bacterial adhesion and good long persistent photocatalysis activity are observed in the Zn₂ GeO₄ :Mn radiated dendrites, which endows Zn₂ GeO₄ :Mn with persistent antibacterial activity even in the dark. Further, the Zn₂ GeO₄ :Mn spike flowers loaded fabrics exhibit potent persistent antibacterial properties. Mask and towel fabricated with the antibacterial fabrics can inhibit bacterial growth effectively and no bacteria are observed to pass through the antibacterial mask, suggesting that antibacterial mask can guarantee our health and can be utilized repeatedly. The developed Zn₂ GeO₄ :Mn dendrites possess ideal ability in long-term bacterial inhibition, making them valuable in the fields of medical protection and food packaging.