Spectroscopic Definition of a Highly Reactive Site in Cu-CHA for Selective Methane Oxidation: Tuning a Mono-μ-Oxo Dicopper(II) Active Site for Reactivity

Abstract

Using UV-vis and resonance Raman spectroscopy, we identify a [Cu₂O]²⁺ active site in O₂ and N₂O activated Cu-CHA that reacts with methane to form methanol at low temperature. The Cu-O-Cu angle (120°) is smaller than that for the [Cu₂O]²⁺ core on Cu-MFI (140°), and its coordination geometry to the zeolite lattice is different. Site-selective kinetics obtained by operando UV-vis show that the [Cu₂O]²⁺ core on Cu-CHA is more reactive than the [Cu₂O]²⁺ site in Cu-MFI. From DFT calculations, we find that the increased reactivity of Cu-CHA is a direct reflection of the strong [Cu₂OH]²⁺ bond formed along the H atom abstraction reaction coordinate. A systematic evaluation of these [Cu₂O]²⁺ cores reveals that the higher O-H bond strength in Cu-CHA is due to the relative orientation of the two planes of the coordinating bidentate O-Al-O T-sites that connect the [Cu₂O]²⁺ core to the zeolite lattice. This work along with our earlier study ( <i>J. Am. Chem. Soc</i>, 2018, 140, 9236-9243) elucidates how zeolite lattice constraints can influence active site reactivity.