Lattice Strain Leads to High Thermoelectric Performance in Polycrystalline SnSe

Abstract

Polycrystalline SnSe materials with <i>ZT</i> values comparable to those of SnSe crystals are greatly desired due to facile processing, machinability, and scale-up application. Here manipulating interatomic force by harnessing lattice strains was proposed for achieving significantly reduced lattice thermal conductivity in polycrystalline SnSe. Large static lattice strain created by lattice dislocations and stacking faults causes an effective shortening in phonon relaxation time, resulting in ultralow lattice thermal conductivity. A combination of band convergence and resonance levels induced by Ga incorporation contribute to a sharp increase of Seebeck coefficient and power factor. These lead to a high thermoelectric performance <i>ZT</i> ∼ 2.2, which is a record high <i>ZT</i> reported so far for solution-processed SnSe polycrystals. Besides the high peak <i>ZT</i>, a high average <i>ZT</i> of 0.72 and outstanding thermoelectric conversion efficiency of 12.4% were achieved by adopting nontoxic element doping, highlighting great potential for power generation application at intermediate temperatures. Engineering lattice strain to achieve ultralow lattice thermal conductivity with the aid of band convergence and resonance levels provides a great opportunity for designing prospective thermoelectrics.