Concepedia

Radical 1,2-addition of bromoarenes to alkynes <i>via</i> dual photoredox and nickel catalysis

Lei Xu, Shengqing Zhu, Liping Huo, Fan Chen, Wei Yu, Lingling Chu

Organic Chemistry Frontiers · 2021 · 24 citations · 68 references

DOI

Concepts

Abstract

A 1,2-addition of aryl bromides to alkynes enabled by the photocatalytic generation of bromine radicals <italic>via</italic> photoredox and nickel catalysis is reported.

References

68

Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis

K. C. Nicolaou, Paul G. Bulger, David Šarlah · Angewandte Chemie International Edition · 2005 · 2.7K citations

, , +9

Copper/Amino Acid Catalyzed Cross-Couplings of Aryl and Vinyl Halides with Nucleophiles

Dawei Ma, Qian Cai · Accounts of Chemical Research · 2008 · 1.1K citations

Simple and selective method for aldehydes (RCHO) .fwdarw. (E)-haloalkenes (RCH:CHX) conversion by means of a haloform-chromous chloride system

Kazuhiko Takai, Koji Nitta, K. UTIMOTO · Journal of the American Chemical Society · 1986 · 747 citations

, , +10

Naturally Occurring Organohalogen Compounds

Gordon W. Gribble · Accounts of Chemical Research · 1998 · 672 citations

, , +14

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling

Patricia Zhang, Chi “Chip” Le, David W. C. MacMillan · Journal of the American Chemical Society · 2016 · 664 citations · Full text

, , +16