Nickel-catalyzed reductive benzylation of tertiary alkyl halides with benzyl chlorides and chloroformates - Concepedia

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Nickel-catalyzed reductive benzylation of tertiary alkyl halides with benzyl chlorides and chloroformates

25

Citations

43

References

2021

Year

Jiabao Wang, Yuxin Gong, Deli Sun, Hegui Gong

Organic Chemistry Frontiers

Chemical EngineeringCross-coupling ReactionEngineeringNi-catalyzed Cross-electrophile CouplingTertiary Alkyl HalidesNickel-catalyzed Reductive BenzylationOrganic ChemistryOrganometallic CatalysisCatalysisChemistryHalogenationBenzyl Chlorides-Quaternary Carbon Centers

Abstract

We report a Ni-catalyzed cross-electrophile coupling of benzyl chlorides and chloroformates with unactivated tertiary alkyl halides to forge the challenging benzylated all C(sp<sup>3</sup>)-quaternary carbon centers.

References

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