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All‐Solid‐State Batteries: New Cost‐Effective Halide Solid Electrolytes for All‐Solid‐State Batteries: Mechanochemically Prepared Fe<sup>3+</sup>‐Substituted Li<sub>2</sub>ZrCl<sub>6</sub> (Adv. Energy Mater. 12/2021)
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2021
Year
All-solid-state BatteriesEngineeringAll‐solid‐state BatteriesChemistryAqueous BatteryChemical EngineeringSodium BatteryMaterials ScienceBattery Electrode MaterialsHalide Superionic ConductorsLithium-ion BatteryBattery AdditivesLithium-ion BatteriesAdvanced Electrode MaterialEnergy StorageSolid-state BatteryElectrochemistryLi-ion Battery MaterialsFe3+-substituted Li2zrcl6Cathode MaterialsEnergy MaterBatteriesAnode Materials
In article number 2003190, Kyung-Wan Nam, Yoon Seok Jung and co-workers develop a new halide solid electrolyte, Fe3+-substituted Li2ZrCl6, that is mechanically sinterable, (electro)chemical-oxidation tolerant, and free of rare-earth metals. The outstanding performance of the all-solid-state batteries using LiCoO2 and LiNi0.88Co0.11Al0.01O2 is enabled by the use of the newly developed halide superionic conductors.