Preparation of N/S doped carbon dots and their application in nitrite detection

Abstract

Detection of carcinogens is generally recognized to be meaningful, especially for nitrites (NO₂ ^-). Here blue-green fluorescent carbon dots (CDs) were successfully synthesized by using <i>p</i>-aminobenzenesulfonic acid, and their surfaces were identified to be abundant in the functional groups of amino, hydroxyl, and sulfuric acid. Importantly, the sulfuric acid group and aromatic primary ammonia groups on the surfaces of CDs showed the interactions with the nitrites to cause fluorescence quenching. The novel CDs showed high sensitivity and selectivity for NO₂ ^- detection with a low detection limit of 0.03 mM in water due to the fluorescence quenching effect of the CDs. Consequently, the proposed CDs here may provide a new way of monitoring NO₂ ^- in the target samples.