Physical Review Letters · 2021 · 268 citations · 40 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsSolid State PhysicsSolid-state ChemistryElectron-phonon InteractionsHigh-temperature MaterialsMetalsSolid-state SynthesisSuperconducting MaterialsSuperconducting Thin FilmsCritical TemperatureHigh-temperature SuperconductivityHigh-temperature SuperconductorsHydrogenationHydrogenation CatalysisHydrogenation ReactionsPhonon-mediated SuperconductivitySuperconducting Critical Temperature
The recent observation of room-temperature superconductivity will undoubtedly lead to a surge in the discovery of new, dense, hydrogen-rich materials. The rare earth metal superhydrides are predicted to have very high-T_{c} superconductivity that is tunable with changes in stoichiometry or doping. Here we report the synthesis of an yttrium superhydride that exhibits superconductivity at a critical temperature of 262 K at 182±8 GPa. A palladium thin film assists the synthesis by protecting the sputtered yttrium from oxidation and promoting subsequent hydrogenation. Phonon-mediated superconductivity is established by the observation of zero resistance, an isotope effect and the reduction of T_{c} under an external magnetic field. The upper critical magnetic field is 103 T at zero temperature.
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