Concepedia

Publication | Closed Access

AgBi(SO<sub>4</sub>)(IO<sub>3</sub>)<sub>2</sub>: aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement

DOI

33

Citations

54

References

2021

Year

Hongming Liu, Qingchen Wu, Lili Liu, Zheshuai Lin, P. Shiv Halasyamani, Xingguo Chen, Jingui Qin
Chemical Communications

Abstract

A new 3D noncentrosymmetric mixed-metal sulfate iodate, AgBi(SO<sub>4</sub>)(IO<sub>3</sub>)<sub>2</sub>, has been designed based on a 2D iodate of AgBi(IO<sub>3</sub>)<sub>4</sub>via the aliovalent substitution of [IO<sub>3</sub>]<sup>-</sup> groups by [SO<sub>4</sub>]<sup>2-</sup> groups. Enhancement of the second harmonic generation response (3.0 × KDP to 3.9 × KDP) has been achieved while retaining a favorable NLO framework. This is a novel strategy to upgrade structural dimensions.

References

YearCitations

Page 1