A Photoluminescent Cd(II) Coordination Polymer with Potential Active Sites Exhibiting Multiresponsive Fluorescence Sensing for Trace Amounts of NACs and Fe³⁺ and Al³⁺ Ions

Abstract

The elaborately designed π-electron-rich fluorescent ligand 1,4-bis(1-carboxymethylene-4-imidazolyl)benzene (H₂L), possessing bifunctional groups including the carboxylate groups (building units) and 4-imidazoyl groups (N-donor potential active sites) has been employed to construct fluorescent coordination polymers. A luminescent sensor, namely [Cd(L)(phen)₂]·5H₂O (<b>1</b>), was obtained, which has a one-dimensional structure. The fluorescent material shows a blue emission maximum at 457 nm with a luminescence lifetime of 488 ns and a quantum yield (QY) of 4.56%. Significantly, <b>1</b> serves as a promising multiresponsive luminescent sensor to detect trace nitroaromatic compounds (NACs) with the limits of detection (LOD) of 7.21 × 10^-8, 1.85 × 10^-5, and 1.15 × 10^-5 mol/L for 2-nitrophenol (2-NP), 3-nitrophenol (3-NP), and 4-nitrophenol (4-NP), respectively. Furthermore, CP <b>1</b> exhibits fluorescent turn-off and turn-on sensing behavior for Fe³⁺ and Al³⁺ metal ions with trace amounts of 1.05 × 10^-7 and 1.13 × 10^-7 mol/L, respectively. Experimental methods and theoretical calculations were employed to elucidate the sensing mechanism in detail.