Chemical Science · 2021 · 46 citations · 101 references
Natural SciencesChemistryCatalysisOrganic ChemistryStructure-activity RelationshipsCatalytic MechanismsCatalytic Reaction KineticsReaction Mechanism ModelingReaction MechanismsReaction PathwaysTransition Metal ChemistryC-h ActivationC-h Bond ActivationCatalytic Reaction MechanismsDirected C - H ActivationRate-determining StepSteric ConstraintsStructure-reactivity RelationshipsTransition Metal Catalysis
The term and concept of Ortho Effect (OE) is introduced for the description of steric effects in transition metal catalyzed directed<italic>ortho</italic>C–H activation reactions to explain and predict reactivities of substrates.
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