Combinatorial measurement of critical cooling rates in aluminum-base metallic glass forming alloys

Abstract

Direct measurement of critical cooling rates has been challenging and only determined for a minute fraction of the reported metallic glass forming alloys. Here, we report a method that directly measures critical cooling rate of thin film metallic glass forming alloys in a combinatorial fashion. Based on a universal heating architecture using indirect laser heating and a microstructure analysis this method offers itself as a rapid screening technique to quantify glass forming ability. We use this method to identify glass forming alloys and study the composition effect on the critical cooling rate in the Al-Ni-Ge system where we identified Al₅₁Ge₃₅Ni₁₄ as the best glass forming composition with a critical cooling rate of 10⁴ K/s.