Metal–ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co–Si moiety

Abstract

A cobalt-silyl moiety reveals metal-ligand cooperative group transfer to generate isocyanate from the reaction of alkyl azide and CO. This reaction involves the reversible insertion of a nitrene group into a Co-Si bond. Photolysis leads to ligand substitution of a Co(CO)₂ species, allowing the successful catalytic conversion of AdN₃ to AdNCO under CO(g).