New up-conversion luminescence in molecular cyano-substituted naphthylsalophen lanthanide(<scp>iii</scp>) complexes

Abstract

A new naphthylsalophen and its 3 : 2 ligand-to-lanthanide sandwich-type complexes were isolated. When excited at 380 nm, the complexes display the characteristic metal-centred emission for Nd^III, Er^III and Yb^III. Upon 980 nm excitation, in mixed lanthanide and the Er complexes, Er-centred upconversion emission at 543 and 656 nm is observed, with power densities as low as 2.18 W cm^-2.