Coatings · 2021 · 144 citations · 18 references
EngineeringBiomimetic MaterialsFunctional PropertyMechanical EngineeringBio-based MaterialNatural ProductsWater Vapor PermeabilityVegan AlternativesMaterials ScienceTrendy AlternativesFashionBiocompositeArtificial LeatherIndustrial DesignBiomanufacturingMechanical PropertiesWood FibreTechnologyBiomaterialsBio-based MaterialsTechnical Performance
The market for biogenic and synthetic alternatives to leather is expanding to replace animal‑based materials with vegan options, favoring bio‑based raw materials over fossil‑based ones, and the unique multilayer, tightly packed structure of natural leather is believed to underlie its universal performance. The study compares the structure and technical performance of leather, artificial leather, and nine alternative materials to identify suitable application areas. The authors examined a shoe upper leather, an artificial leather, and nine alternative materials, characterizing their structure and composition with microscopy and FTIR spectroscopy and measuring surface properties, mechanical performance, water‑vapor permeability, and water absorption using standardized tests. None of the alternatives matched leather’s universal performance, although some achieved high values in selected properties, and the multilayer structure responsible for leather’s performance has not yet been replicated in synthetic or bio‑based materials.
The market for biogenic and synthetic alternatives to leather is increasing aiming to replace animal-based materials with vegan alternatives. In parallel, bio-based raw materials should be used instead of fossil-based synthetic raw materials. In this study, a shoe upper leather and an artificial leather, and nine alternative materials (Desserto®, Kombucha, Pinatex®, Noani®, Appleskin®, Vegea®, SnapPap®, Teak Leaf®, and Muskin®) were investigated. We aimed to compare the structure and technical performance of the materials, which allows an estimation of possible application areas. Structure and composition were characterized by microscopy and FTIR spectroscopy, the surface properties, mechanical performance, water vapor permeability, and water absorption by standardized physical tests. None of the leather alternatives showed the universal performance of leather. Nevertheless, some materials achieved high values in selected properties. It is speculated that the grown multilayer structure of leather with a very tight surface and a gradient of the structural density over the cross-section causes this universal performance. To date, this structure could neither be achieved with synthetic nor with bio-based materials.
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