<i>sp</i>^<i>3</i><i>Bis</i>‐Organometallic Reagents via Catalytic 1,1‐Difunctionalization of Unactivated Olefins

Abstract

A catalytic 1,1-difunctionalization of unactivated olefins en route to sp³ bis-organometallic B,B(Si)-reagents is described. The protocol is characterized by exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, constituting a new platform to access sp³ bis-organometallics.