Electric-field-assisted processing of ceramics: Nonthermal effects and related mechanisms

TLDR

Field‑assisted processing such as spark plasma and flash sintering has broadened ceramic engineering, with high electric currents producing rapid Joule heating. This study investigates nonthermal effects of electric fields on fluorite‑ and perovskite‑based ceramics. The authors discuss how electric fields alter defect chemistry, ion transport, and conductivity, driving electrochemical reactions, phase changes, and sintering kinetics even at constant temperature. They show that ion‑driven changes in grain‑boundary segregation can both retard and accelerate grain growth, enabling graded microstructures.

Abstract

Abstract Field-assisted processing methods, such as spark plasma sintering and flash sintering, have considerably expanded the toolbox of ceramic engineering. Depending on the conditions, substantial electric currents may flow through the material resulting in fast heating rates due to Joule heating. Here, we focus on nonthermal effects induced by electric fields during processing of fluorite- and perovskite-based ceramics. The fundamentals of how a field can directly modify defect formation and migration in crystals are discussed. In addition, the interplay of ion transport and electrical conductivity is considered, this interplay being crucial to understanding nonthermal effects caused by electric fields (as in memristive switching). Electrochemical reactions leading to new phases or reduction are also described, as are densification rates and sintering parameters that are significantly affected even though the sample temperature is held constant. Finally, as grain-boundary properties and segregation are changed by ion transport, we describe how both retardation and acceleration of grain growth can be achieved including graded microstructures.