Corrosion Inhibition Effect of Ethyl 1-(4-chlorophenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylate on Aluminium Alloy in Hydrochloric Acid

Abstract

The inhibition efficiency of Ethyl 1-(4-chlorophenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylate (ETC) on AA6061 Aluminium (Al) alloy in 0.1M HCl solution was tested through weight loss, potentiodynamic polarisation and electrochemical impedance spectroscopy methods. The experimental results show that the inhibition efficiency of ETC increased with an increase in inhibitors concentration and temperature. Potentiodynamic polarisation indicated that the inhibitor is mixed type. From Langmuir isotherm, it was hypothesized the adsorption of inhibitors on AA6061 alloy surface might occur by physical and chemical interaction; however, the activation energy raised suggests a chemisorption process for the interaction of the inhibitor on AA6061 alloy surface. Scanning electron microscopy was used to characterise the surface morphology of the alloy in presence and in the absence of the inhibitor.