Superhydrophobic Surface-Constructed Membrane Contactor with Hierarchical Lotus-Leaf-Like Interfaces for Efficient SO₂ Capture

Abstract

An organic-inorganic polyvinylidene fluoride/polyvinylidene fluoride-silica (PVDF/PVDF-SiO₂) mixed matrix membrane contactor is fabricated via a facile and efficient hydrophobic modification method. The solubility parameters of the PVDF particle are precisely regulated, the PVDF particles are blended with SiO₂ nanoparticles to form PVDF-SiO₂ suspension, and then the suspension is introduced onto the surface of the PVDF substrate by an <i>in situ</i> spin coating strategy. The PVDF particles are partly etched and incorporated to construct the adhesive PVDF-SiO₂ core-shell layer on the PVDF substrate, which results in a more stable PVDF-SiO₂ coating layer on the substrate. The surface structure is precisely regulated by changing the etching morphology of PVDF particles and amount of doped PVDF and SiO₂ particles, forming an integrated porous PVDF-SiO₂ layer and constructing hierarchical lotus-leaf-like interfaces. The resultant PVDF/PVDF-SiO₂ membrane contactors display the relatively regular distribution of pore size with ∼420 nm and excellent hydrophobic property with a water contact angle of ∼158°, which noticeably lightens wetting phenomena of membrane contactors. The SO₂ absorption fluxes can reach as high as 1.26 × 10^-3 mol·m^-2·s^-1 using 0.625 M of ethanolamine (EA) as liquid absorbent. The high stability of the SO₂ absorption flux test indicates the excellent interface compatibility between the PVDF-SiO₂ coating layer and the PVDF substrate. The versatile organic-inorganic layer exhibits super hydrophobic property, which prevents wetting of membrane pores. In addition, the membrane mass transfer resistance (<i>H</i>/<i>K</i>_m) and membrane phase transfer coefficient (<i>K</i>_m) are explored.