Coupling of Cu(100) and (110) Facets Promotes Carbon Dioxide Conversion to Hydrocarbons and Alcohols

Abstract

Copper can efficiently electro-catalyze carbon dioxide reduction to C₂₊ products (C₂ H₄ , C₂ H₅ OH, n-propanol). However, the correlation between the activity and active sites remains ambiguous, impeding further improvements in their performance. The facet effect of copper crystals to promote CO adsorption and C-C coupling and consequently yield a superior selectivity for C₂₊ products is described. We achieve a high Faradaic efficiency (FE) of 87 % and a large partial current density of 217 mA cm^-2 toward C₂₊ products on Cu(OH)₂ -D at only -0.54 V versus the reversible hydrogen electrode in a flow-cell electrolyzer. With further coupled to a Si solar cell, record-high solar conversion efficiencies of 4.47 % and 6.4 % are achieved for C₂ H₄ and C₂₊ products, respectively. This study provides an in-depth understanding of the selective formation of C₂₊ products on Cu and paves the way for the practical application of electrocatalytic or solar-driven CO₂ reduction.