Publication | Closed Access
Catalytic Dimerization of Acrylonitrile
50
Citations
4
References
1997
Year
Catalytic DimerizationEngineeringNew Catalytic SystemCatalytic SynthesisSelective DimerizationOrganic ChemistryOrganometallic CatalysisCatalysisCombination Rucl2ChemistryMolecular CatalysisAsymmetric CatalysisSynthetic ChemistryBiomolecular Engineering
A new catalytic system using the combination RuCl2(DMSO)4/CH3CH2COONa/DMSO/carboxylic acid which enables selective dimerization of acrylonitrile to linear dimers without formation of propionitrile as a byproduct has been developed on the basis of a new working hypothesis of the desirable reaction mechanism involving protonolysis of a C−Ru bond in the intermediate.
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