Sign reversal in the exchange bias and the collapse of hysteresis width across the magnetic compensation temperature in a single crystal of Nd0.75Ho0.25Al2

Abstract

In the admixed Nd0.75Ho0.25Al2 system, magnetic moments of Nd and Ho occupying the same crystallographic site are antiferromagnetically coupled and the chosen stoichiometry displays a magnetic compensation behavior (Tcomp of about 24 K) in all orientations. In the vicinity of Tcomp, the conduction electron polarization (CEP) assumes the role of a soft ferromagnet exchange coupled to a pseudo-antiferromagnet comprising Nd/Ho moments, resulting in an asymmetry in the hysteretic (M-H) loop, i.e., the notion of an exchange bias field (Hexch). Across Tcomp, the CEP contribution reverses sign, and in consonance, the asymmetry in the M-H loop also undergoes a phase reversal. Interestingly, the width of the M-H loop shows a divergence, followed by a collapse on approaching Tcomp from either end. The observed behavior confirms a long standing prediction based on a phenomenological model for ferrimagnetic systems. The field induced changes across Tcomp leave an imprint of a quasi-phase transition in the heat capacity data. Magneto-resistance (ΔR / R vs T) has an oscillatory response, in which the changes across Tc and Tcomp can be recognized.