ACS Omega · 2020 · 43 citations · 64 references
Natural SciencesChemical EngineeringChemistryBiocatalysisCatalysisOrganic ChemistryOrganic SynthesisPhotocatalysisPhotochemical SynthesisPhotochemistryElectron-donating GroupsElectron-withdrawing GroupsMetal-free CatalystsMild Reaction ConditionsMulticomponent Reaction ChemistryPhotocatalyst DesignPhotocatalytic SynthesisVisible-light Photocatalysis
-butyl isocyanide under visible light using eosin Y as a photocatalyst has been developed. Inexpensive, nontoxic, the effortless accessibility of starting materials, and nonparticipation of particular glassware and a photoreactor system are important qualities of the current approach. Strangely, the mild conditions, environment-friendly, and enumerating tolerance of an extensive range of both electron-donating and electron-withdrawing groups are additional features of the approach.
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Photoredox Catalysis in Organic Chemistry
Megan H. Shaw, Jack Twilton, David W. C. MacMillan · The Journal of Organic Chemistry · 2016 · 3.1K citations · Full text
Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer
Gilbert J. Choi, Qilei Zhu, David C. Miller et al. · Nature · 2016 · 770 citations · Full text