In-situ synthesis of Fe₂O₃/rGO using different hydrothermal methods as anode materials for lithium-ion batteries

Abstract

Abstract This paper studies in-situ synthesis of Fe 2 O 3 /reduced graphene oxide (rGO) anode materials by different hydrothermal process.Scanning Electron Microscopy (SEM) analysis has found that different processes can control the morphology of graphene and Fe 2 O 3 . The morphologies of Fe 2 O 3 prepared by the hydrothermal in-situ and oleic acid-assisted hydrothermal in-situ methods are mainly composed of fine spheres, while PVP assists The thermal in-situ law presents porous ellipsoids. Graphene exhibits typical folds and small lumps. X-ray diffraction analysis (XRD) analysis results show that Fe 2 O 3 /reduced graphene oxide (rGO) is generated in different ways. Also, the material has good crystallinity, and the crystal form of the iron oxide has not been changed after adding GO. It has been reduced, and a characteristic peak appears around 25°, indicating that a large amount of reduced graphene exists. The results of the electrochemical performance tests have found that the active materials prepared in different processes have different effects on the cycle performance of lithium ion batteries. By comprehensive comparison for these three processes, the electro-chemical performance of the Fe 2 O 3 /rGO prepared by the oleic acid-assisted hydrothermal method is best.