A highly stable polyoxovanadate-based Cu(<scp>i</scp>)–MOF for the carboxylative cyclization of CO₂with propargylic alcohols at room temperature

Abstract

A POVs-based Cu(<sc>i</sc>)–MOF was synthesized and utilized as a heterogeneous catalyst for the cyclization of CO₂with propargylic alcohols to obtain value-added α-alkylidene cyclic carbonates, exhibiting high catalytic activity and sustainability.