Concepedia

A highly stable polyoxovanadate-based Cu(<scp>i</scp>)–MOF for the carboxylative cyclization of CO<sub>2</sub>with propargylic alcohols at room temperature

Hong‐Rui Tian, Zhong Zhang, Shumei Liu, Shumei Liu, Tian‐Yi Dang, Zhuo Li, Ying Lü, Shuxia Liu, Shuxia Liu

Green Chemistry · 2020 · 72 citations · 62 references

DOI

Concepts

Abstract

A POVs-based Cu(<sc>i</sc>)–MOF was synthesized and utilized as a heterogeneous catalyst for the cyclization of CO<sub>2</sub>with propargylic alcohols to obtain value-added α-alkylidene cyclic carbonates, exhibiting high catalytic activity and sustainability.

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