Publication | Open Access
A green route to polyurethanes: oxidative carbonylation of industrially relevant aromatic diamines by CO<sub>2</sub>-based methyl formate
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Citations
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References
2020
Year
EngineeringGreen ChemistryOrganic ChemistryChemistryLiquid SourceRelevant Aromatic DiaminesChemical EngineeringSustainable SynthesisOrganometallic CatalysisMethyl FormatePolymer ChemistryGreen RouteCo/meoh MixturesCatalysisCatalytic SynthesisBiomolecular EngineeringSustainable PolymerIntermediate Methyl FormateHalogenationSynthetic Chemistry
Toluene-2,4-diamine, 4,4′-methylenedianiline and 2,4-diaminomesitylene were converted directly into the corresponding dicarbamates<italic>via</italic>the CO<sub>2</sub>-based intermediate methyl formate (MF) which can be regarded as a liquid source for CO/MeOH mixtures.
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