Design of a Single‐Atom Indium^δ+–N₄Interface for Efficient Electroreduction of CO₂to Formate

Abstract

Main-group element indium (In) is a promising electrocatalyst which triggers CO₂ reduction to formate, while the high overpotential and low Faradaic efficiency (FE) hinder its practical application. Herein, we rationally design a new In single-atom catalyst containing exclusive isolated In^δ+ -N₄ atomic interface sites for CO₂ electroreduction to formate with high efficiency. This catalyst exhibits an extremely large turnover frequency (TOF) up to 12500 h^-1 at -0.95 V versus the reversible hydrogen electrode (RHE), with a FE for formate of 96 % and current density of 8.87 mA cm^-2 at low potential of -0.65 V versus RHE. Our findings present a feasible strategy for the accurate regulation of main-group indium catalysts for CO₂ reduction at atomic scale.