Super protective anti-bacterial coating development with silica–titania nano core–shells

Abstract

In the present study, we have developed an anti-bacterial as well as mechanically-strengthened super protective coating material, which can be used as a marine antifouling paint. In this research, silica, titania and silica-titania core-shell nanoparticles were individually prepared <i>via</i> sol-gel and peptization processes. The idea behind the synthesis of core-shell nanoparticles was to utilize the mechanical strength of silica and the antimicrobial property of TiO₂ together. These nanoparticles were characterized <i>via</i> dynamic light scattering, UV-Visible spectroscopy, X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. Coating formulations were developed with two types of model binders, <i>i.e.</i>, solvent-based polyurethane and water-based poly-acrylic, containing all nanoparticles individually at various concentrations for a better comparative study. These coating formulations were applied onto mild steel for anti-bacterial testing that was performed against <i>Escherichia coli</i> and <i>Bacillus</i>. The nanoparticle concentration was varied from 1% (wt) to 6% (wt). The best anti-bacterial result was obtained with 4% (wt) of silica-titania core-shell nanoparticles prepared <i>via</i> the peptization process among all the nanoparticles. The scratch testing was performed successfully using an Erichsen scratch tester; the formulated PU coating passed up-to 20 N load with good adhesion, impact resistance, flexibility and has shown satisfactory anti-corrosion performance.